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  • 产品名称:Ossila材料PDCBT

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PDCBT is a medium-to-wide bandgap polymer semiconductor that belongs to the polythiophene family. With two electron-withdrawing carboxylate side groups, PDCBT is relatively electron deficient when it is compared with P3HT. PDCBT has a main absorption peak (in film) located at 551 nm, 37 nm red-shifted compared to that of P3HT.

PDCBT has been used in highly efficient fullerene free polymer solar cells. These have achieved device power conversion efficiency of 10.16% with ITIC used as the non-fullerene acceptor [6]. Ta-WOdoped PDCBT has been reported as efficient low-loss hole transport layer in hybrid organohalide lead perovskite solar cell not only to enhance the device performance achieving maximum efficiencies of 21.2% but also offering more than 1000 hours of light stability with almost 95% of its efficiency maintained [7]

Device structure: ITO/C60-SAM/perovskite/PDCBT/Ta-WOx/Au


Thickness (nm)

VOC (V) JSC (mA cm-2) FF (%) PCE (%)
650
1.17 22.7 80 21.2

General Information

Full name Poly[2,2''''-bis[[(2-butyloctyl)oxy]carbonyl][2,2':5',2'':5'',2'''-quaterthiophene] -5,5'''-diyl]
Synonyms PDCBT
Chemical formula (C42H56O4S4)n
CAS number 1609536-17-5
HOMO / LUMO HOMO = -5.26 eV, LUMO = -3.0 eV [1]
Solubility Chloroform, chlorobenzene and dichlorobenzene
Absorption λmax 551 nm (in film) [2]
Form Brown reddish flakes/powders
Melting point Tm = 282 °C (lit.)
Classification / Family Polythiophenes, Organic semiconducting materials, Medium-to- wide bandgap polymers, Organic photovoltaics, Polymer solar cells, Perovskite solar cells, Hole-transport layer materials, NF-PSCs, All-polymer solar cells (all-PSCs).

Batch details

Batch Mw Mn PDI Stock Info
M2233A1 101,375 40,659 2.49 In stock


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